In Fallout 4, there are a few anti-PA options, but the handmade rifle is the only automatic option (and I am done with this quarantine lets go to disney ariel shirt bumps it down to 5.56). The hunting rifle should work by default, and can be rechambered in .50 if you want to have absolutely no doubts. The Gauss Rifle is most likely able to punch through armor with ease, though both the guns and their armmo are exceedingly rare. Energy weapons in general do good against armor, but the Minutemen’s cobbled together Laser Musket may actually be better than usual due to it’s ability to dump so much energy onto one single spot. Finally, there are the explosive options such as rockets and mines.
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The NCR have a much easier time of things. While the Minutemen would largely need to scrounge forth their anti-PA I am done with this quarantine lets go to disney ariel shirt , the NCR can have them produced them and deploy them to the few areas where the BoS are known operate. The NCR has everything the Minutemen can get (minus Laser Muskets) plus the Brush Gun and an actual Anti-Materiel rifle. As a side note on the BoS “misusing” PA, they kind of are but they probably have the highest PA:soldier ratio of any organization before or after the war. The BoS does use PA to let soldiers handle heavy weapons, but they have enough PA that even “standard” Knights and Paladins can also use it just for what survivability it does provide.